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Aminothiazole Ligand-Type Dioxo-Mo(VI) Complex Anchored on TiO2 Nanotubes for Selective Oxidation of Monoterpenes with Light and O2

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dc.contributor.authorMartinez-Quiñonez, Henry
dc.contributor.authorAmaya, Alvaro A.
dc.contributor.authorPaez-Mozo, Edgar A.
dc.contributor.authorMartinez-Ortega, Fernando
dc.contributor.researchgroupCiencias UDESspa
dc.date.accessioned2022-08-03T14:59:26Z
dc.date.available2022-08-03T14:59:26Z
dc.date.issued2022-06-27
dc.descriptionDigitalspa
dc.description.abstractSelective Oxygen Atom Transfer to α-pinene, β-pinene, (R)-limonene and camphene by dioxo-Mo(VI)Ln complex {Ln = 2-aminothiazole-4-carboxylic acid} anchored on TiO2 nanotubes (TiO2-NT) using O2 as oxidant and UV light was studied at ambient conditions. The Catalytic system was characterized by FTIR, 1H NMR and 13C, and elemental analysis. Molecular oxygen reoxidizes the (Mo(IV)=O) reduced unit in the darkness, forming an oxo-peroxo-Mo intermediate. The catalyst under UV radiation transfers two oxygen atoms to the olefin. The α-pinene is found to be the most reactive monoterpene.spa
dc.description.researchareaCiencias Médicas y de la Saludspa
dc.format.mimetypeapplication/pdfspa
dc.identifier.doihttps://doi.org/10.1007/s11244-022-01656-9
dc.identifier.issn1022-5528
dc.identifier.issn-l1572-9028
dc.identifier.urihttps://repositorio.udes.edu.co/handle/001/7330
dc.language.isoengspa
dc.publisher.placeSuizaspa
dc.relation.citesMartinez Quiñonez, H., Amaya, Á., Paez-Mozo, E.A. et al. Aminothiazole Ligand-Type Dioxo-Mo(VI) Complex Anchored on TiO2 Nanotubes for Selective Oxidation of Monoterpenes with Light and O2. Top Catal (2022). https://doi.org/10.1007/s11244-022-01656-9
dc.relation.indexedScopusspa
dc.relation.ispartofjournalSpringer Linkspa
dc.relation.ispartofjournalTopics in Catalysis
dc.rights© The Authors, Springer Nature Switzerland AG. Part of Springer Nature, 2022spa
dc.rights.accessrightsinfo:eu-repo/semantics/closedAccessspa
dc.rights.creativecommonsAtribución-NoComercial 4.0 Internacional (CC BY-NC 4.0)spa
dc.rights.urihttps://creativecommons.org/licenses/by-nc/4.0/spa
dc.sourcehttps://link.springer.com/article/10.1007/s11244-022-01656-9spa
dc.subject.proposalAminothiazole ligandeng
dc.subject.proposalDioxo-molybdenum complexeseng
dc.subject.proposalTiO2 nanotubeseng
dc.subject.proposalSelective oxidationeng
dc.titleAminothiazole Ligand-Type Dioxo-Mo(VI) Complex Anchored on TiO2 Nanotubes for Selective Oxidation of Monoterpenes with Light and O2spa
dc.typeArtículo de revistaspa
dc.type.coarhttp://purl.org/coar/resource_type/c_6501spa
dc.type.contentTextspa
dc.type.driverinfo:eu-repo/semantics/articlespa
dc.type.redcolhttp://purl.org/redcol/resource_type/ARTspa
dc.type.versioninfo:eu-repo/semantics/publishedVersionspa
dcterms.audienceTodas las Audienciasspa
dspace.entity.typePublication
oaire.accessrightshttp://purl.org/coar/access_right/c_14cbspa
oaire.versionhttp://purl.org/coar/version/c_970fb48d4fbd8a85spa
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